CAS NO.762-72-1 Allyl Trimethylsilane

CAS NO.762-72-1 Allyl Trimethylsilane

CAS NO.762-72-1 Trimethyl Allyloxysilane BOILING POINT: 85-86° EINECS NUMBER: 212-104-5 MOLECULAR WEIGHT: 114.26 SPECIFIC GRAVITY: 0.7193 FLASHPOINT: 7°C (45°F) HMIS KEY: 2-4-0-X HYDROLYTIC SENSITIVITY: 2: REACTS WITH AQUEOUS ACID FORMULA: C 6 H 14 SI REFRACTIVE INDEX: 1.4074 TSCA: TSCA...
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Product Details


CAS NO.762-72-1 Trimethyl Allyloxysilane Basic  information

Product    Name

Trimethyl Allyloxysilane 

 

Synonyms

Allyltrimethylisilane;trimethyl-prop-2-enyl-silane;Allyltrimethylsilane(3-trimethylsilyl-1-propene)99%available;Allyltrimethylsilane, 98+%;Allyltrimethylsilane,99%;Allyltrimethylsilane,97%;Allyltrimethylsilane,3-(Trimethylsilyl)propene;triMethyl(prop-2-en-1-yl)silane

Structure

    

image001.gif

CAS    NO

762-72-1

Appearance

Colorless    and transparent liquid

Assay

98%min

MF:

C6H14Si

MW

114.26

EINECS

212-104-5

Product    Categories

Organosilicon;Self Assembly&Contact Printing;Self-Assembly Materials;SilanesOrganometallic Reagents;Trialkoxysilanes; Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Self Assembly &;Self-Assembly Materials;Silanes;

Storage

Shading,    sealed, dry place.

Capacity

1000KG    /month

Package

In    paper drums /Fluoride drums /iron drums /plastic drums/IBC Tank ,etc.

Shipment method

By    Sea ,Air ,Courier door to door ,etc.

Loading    Port

China    any port ,Beijing ,Shanghai ,Hong Kong etc.

Application

As    additive used in advanced functional materials.



CAS NO.762-72-1 Trimethyl Allyloxysilane

BOILING POINT: 85-86°

EINECS NUMBER: 212-104-5

MOLECULAR WEIGHT: 114.26

SPECIFIC GRAVITY: 0.7193

FLASHPOINT: 7°C (45°F)


image002.jpg

 

APPLICATION: KEY REVIEWS.1,2,3,4

CARRIES OUT DEOXYGENATIVE ALLYLATION OF BENZYLIC ALCOHOLS.10
ALLYLATES LITHIUM ALKOXIDES W/ LOSS OF THE LITHIUM OXIDE.11
FORMS BENZYLIC HOMOALLYLIC ALCOHOLS IN A 3-COMPONENT REACTION W/ ALDEHYDES.12
DIALLYLATES KETONES VIA THEIR KETALS.13
UNDERGOES POLYMERIZATION WITH ZIRCONOCENE COMPLEXES.5
PROVIDES FUNCTIONAL TERMINATION OF LIVING CARBOCATIONIC POLYMERIZED POLYISOBUTYLENES.6
ALLYLATES DIOXOLANES.7
ALLYLATES IMINES UNDER FLUORIDE CATALYSIS.8
PROVIDES ALTERNATIVE FOR THE FORMATION OF TRANS-ALLYL-2,3-O-ISOPROPYLIDENE-PROTECTED PYRROLIDINES.9

REFERENCE: 1. HANDBOOK FOR REAGENTS FOR ORGANIC SYNTHESIS, REAGENTS FOR SILICON-MEDIATED ORGANIC SYNTHESIS, FUCHS, P. L. ED., JOHN WILEY AND SONS, LTD., 2011, P. 14-24.
10. DE, S. K.; GIBBS, R. A. TETRAHEDRON LETT. 2005, 46, 8345.
11. KABALKA, G. W. ET AL. ORGANOMETALLICS 2007, 26, 4112.
12. KATAKI, D.; PHUKAN, P. TETRAHEDRON LETT. 2009, 50, 1958.
13. GALY, N. ET AL. TETRAHEDRON 2011, 67, 1448.
2. WEBER, W. IN SILICON REAGENTS FOR ORGANIC SYNTHESIS;SPRINGER-VERLAG: 1983, P173.


Usages:

Neutral propylene by-product

Acid-catalyzed silylations

Used for acids and thiols

Employed in the synthesis of N-trimethylsilylpyridinium triflate an active trimethylsilylating agent

Nafion SAC-13 has been shown to be a recyclable catalyst for the trimethylsilylation of primary, secondary, and tertiary alcohols in excellent yields and short reaction times

Reacts with vinyl bromides to give 1,4-dienes and

Versatile synthon- transfers allyl group, highly nucleophilic double bond

Undergoes polymerization with zirconocene complexes

Provides functional termination of living carbocationic polymerized polyisobutylenes

Allylates dioxolanes

Provides alternative for the formation of trans-allyl-2,3-O-isopropylidene-protected pyrrolidines

Carries out deoxygenative allylation of benzylic alcohols

Allylates imines under fluoride catalysis

Reacts with allyl bromides to give 1,5-dienes

Diallylates ketones via their ketals

Forms benzylic homoallylic alcohols in a 3-component reaction with aldehydes

Allylates lithium alkoxides w/ loss of the lithium oxide

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