CAS NO.754-05-2 Trimethylvinylsilane

CAS NO.754-05-2 Trimethylvinylsilane

CAS NO.754-05-2 Trimethylvinylsilane Viscosity, 20 °C: 0.5 cSt ΔH comb : 4,133 kJ/mol ΔH fus : 7.7 kJ/mol Copolymerization parameters- e,Q: 0.04, 0.029 Forms polymers which can be fabricated into oxygen enrichment membranes Polymerization catalyzed by alkyllithium compounds Reacts w/ azides to...
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Product Details


CAS NO.754-05-2 Trimethylvinylsilane Basic information

Product    Name

Trimethylvinylsilane

 

Synonyms

CH2=CHSi(CH3)3;ethenyltrimethyl-silan;Silane, trimethylvinyl-;silane,trimethylvinyl-;Vinyltrimethysilane;VINYLTRIMETHYLSILANE;(TRIMETHYLSILYL)ETHYLENE;TRIMETHYLVINYLSILANE

Structure

     

image001.gif

CAS    NO

754-05-2

Appearance

Colorless    and transparent liquid

Assay

98%min

MF:

C5H12Si

MW

100.23

EINECS

212-042-9

Product    Categories

Organosilicon;Self Assembly&Contact Printing;Self-Assembly Materials;SilanesOrganometallic Reagents;Trialkoxysilanes; Chemical Synthesis;Contact Printing;Materials Science;Micro/NanoElectronics;Organometallic Reagents;Self Assembly &;Self-Assembly Materials;Silanes;

Storage

Shading,    sealed, dry place.

Capacity

1000KG    /month

Package

In    paper drums /Fluoride drums /iron drums /plastic drums/IBC Tank ,etc.

Shipment method

By    Sea ,Air ,Courier door to door ,etc.

Loading    Port

China    any port ,Beijing ,Shanghai ,Hong Kong etc.

Application

As    additive used in advanced functional materials.



CAS NO.754-05-2 Trimethylvinylsilane 

Viscosity, 20 °C: 0.5 cSt

ΔHcomb: 4,133 kJ/mol

ΔHfus: 7.7 kJ/mol

Copolymerization parameters- e,Q: 0.04, 0.029

Forms polymers which can be fabricated into oxygen enrichment membranes

Polymerization catalyzed by alkyllithium compounds

Reacts w/ azides to form trimethylsilyl-substituted aziridines

Undergoes Heck coupling to (E)-β-substituted vinyltrimethylsilanes, which can then be cross-coupled further

Extensive review of silicon based cross-coupling agents


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APPLICATION: REVIEW OF SYNTHETIC UTILITY.

POLYMERIZATION CATALYZED BY ALKYLLITHIUM COMPOUNDS.
SYNTHETIC REACTIONS OF VINYLSILANES REVIEWED.
UNDERGOES HECK COUPLING TO (E)-?-SUBSTITUTED VINYLTRIMETHYLSILANES, WHICH CAN BE CROSS-COUPLED FURTHER.
REACTS W/ AZIDES TO FORM TRIMETHYLSILYL-SUBSTITUTED AZIRIDINES


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